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Cadmium vs Thallium


Thallium vs Cadmium


Periodic Table

Symbol
Cd  
Tl  

Group Number
12  
6
13  
5

Period Number
5  
6  

Block
d block  
p block  

Element Family
Transition Metal  
Post-​Transition  

CAS Number
7440439  
99+
7440280  
99+

Space Group Name
P63/mmc  
P63/mmc  

Space Group Number
194.00  
5
194.00  
5

Facts

Interesting Facts
  • Naturally occurring minor elements include Cadmium.
  • Cadmium is released into atmosphere to control volcanic eruption and forest fires.
  • It is used for electroplating of Steel for corrosion resistance.
  • It can absorb neutrons and used in nuclear reactor to control atomic fission.
  
  • Compounds of Thallium metal are highly Toxic.
  • Thallium metal is being suspected as a human carcinogen.
  

Sources
Found As a By-product, Found in Minerals, Mining  
Found As a By-product, Ores of metals, Ores of Minerals  

History
  
  

Who Discovered
Karl Samuel Leberecht Hermann and Friedrich Stromeyer  
William Crookes  

Discovery
In 1817  
In 1861  

Abundance
  
  

Abundance In Universe
2 * 10-7 %  
22
5 * 10-9 %  
32

Abundance In Sun
~0.0000006 %  
21
~0.0000001 %  
26

Abundance In Meteorites
0.00 %  
31
0.00 %  
99+

Abundance In Earth's Crust
0.00 %  
99+
0.00 %  
99+

Abundance In Oceans
0.00 %  
28
0.00 %  
34

Abundance In Humans
0.00 %  
11
Not Available  

Uses

Uses & Benefits
  • It has very limited uses as it is a toxic metal and it can cause birth defects, cancer, etc.
  • Almost 80% of Cadmium metal is used in Nickel cadmium Batteries and now it is getting replaced with nickel hydride.
  
  • Thallium is a toxic metal and hence it has limited uses. Thallium metal is mostly used for producing photoelectric cells.
  • In thermometer’s mercury alloy has 8% of thallium, as it has a melting point lower than 20°C.
  

Industrial Uses
Aerospace Industry, Ammunition Industry, Chemical Industry, Electrical Industry, Electronic Industry  
Chemical Industry  

Medical Uses
NA  
Medical Research  

Other Uses
Alloys  
Alloys  

Biological Properties
  
  

Toxicity
Toxic  
Highly Toxic  

Present in Human Body
Yes  
Yes  

In Blood
0.01 Blood/mg dm-3  
24
0.00 Blood/mg dm-3  
34

In Bone
1.80 p.p.m.  
15
0.00 p.p.m.  
33

Physical Properties

Melting Point
320.90 °C  
99+
303.50 °C  
99+

Boiling Point
765.00 °C  
99+
1,457.00 °C  
99+

Appearance
  
  

Physical State
Solid  
Solid  

Color
Silvery Bluish-Gray  
Silvery White  

Luster
Metallic  
NA  

Hardness
  
  

Mohs Hardness
2.00  
16
1.20  
20

Brinell Hardness
203.00 MPa  
39
26.50 MPa  
99+

Speed of Sound
2,310.00 m/s  
39
818.00 m/s  
99+

Optical Properties
  
  

Reflectivity
67.00 %  
11
Not Available  

Allotropes
No  
No  

α Allotropes
Not Available  
Not Available  

β Allotropes
Not Available  
Not Available  

γ Allotropes
Not Available  
Not Available  

Chemical Properties

Chemical Formula
Cd  
Tl  

Isotopes
  
  

Known Isotopes
34  
5
32  
7

Electronegativity
  
  

Pauling Electronegativity
1.69  
17
1.62  
21

Sanderson Electronegativity
1.98  
9
2.25  
5

Allred Rochow Electronegativity
1.46  
15
1.44  
17

Mulliken-Jaffe Electronegativity
1.53  
13
1.96  
6

Allen Electronegativity
1.52  
27
1.79  
13

Electropositivity
  
  

Pauling Electropositivity
2.31  
37
2.38  
33

Ionization Energies
  
  

1st Energy Level
867.80 kJ/mol  
11
589.40 kJ/mol  
99+

2nd Energy Level
1,631.40 kJ/mol  
32
1,971.00 kJ/mol  
14

3rd Energy Level
3,616.00 kJ/mol  
13
2,878.00 kJ/mol  
32

Electrochemical Equivalent
2.10 g/amp-hr  
27
7.63 g/amp-hr  
2

Electron Work Function
4.22 eV  
22
3.84 eV  
28

Other Chemical Properties
Chemical Stability, Anti Corrosion, Ionization, Radioactive Isotopes, Solubility  
Corrosion, Ionization, Radioactive Isotopes, Solubility  

Atomic Properties

Atomic Number
48  
99+
81  
35

Electron Configuration
[Kr] 4d10 5s2  
[Xe] 4f14 5d10 6s2 6p1  

Crystal Structure
Hexagonal Close Packed (HCP)  
Hexagonal Close Packed (HCP)  

Crystal Lattice
HCP-Crystal-Structure-of-Cadmium.jpg#100  
BCC-Crystal-Structure-.jpg#100  

Atom
  
  

Number of Protons
48  
99+
81  
35

Number of Neutrons
64  
99+
123  
20

Number of Electrons
48  
99+
81  
35

Radius of an Atom
  
  

Atomic Radius
151.00 pm  
32
170.00 pm  
22

Covalent Radius
144.00 pm  
40
145.00 pm  
39

Van der Waals Radius
158.00 pm  
99+
196.00 pm  
30

Atomic Weight
112.41 amu  
99+
204.38 amu  
31

Atomic Volume
13.10 cm3/mol  
39
17.20 cm3/mol  
31

Adjacent Atomic Numbers
  
  

Previous Element
Silver
  
Mercury
  

Next Element
Indium
  
Lead
  

Valence Electron Potential
30.00 (-eV)  
99+
9.60 (-eV)  
99+

Lattice Constant
297.94 pm  
99+
345.66 pm  
99+

Lattice Angles
π/2, π/2, 2 π/3  
π/2, π/2, 2 π/3  

Lattice C/A Ratio
1.89  
1
1.60  
6

Mechanical Properties

Density
  
  

Density At Room Temperature
8.65 g/cm3  
99+
11.85 g/cm3  
31

Density When Liquid (at m.p.)
8.00 g/cm3  
28
11.22 g/cm3  
13

Tensile Strength
62.00 MPa  
16
Not Available  

Viscosity
Not Available  
Not Available  

Vapor Pressure
  
  

Vapor Pressure at 1000 K
Not Available  
16.90 (Pa)  
5

Elasticity properties
  
  

Shear Modulus
19.00 GPa  
35
2.80 GPa  
99+

Bulk Modulus
42.00 GPa  
29
43.00 GPa  
28

Young's Modulus
50.00 GPa  
36
8.00 GPa  
99+

Poisson Ratio
0.30  
14
0.45  
2

Other Mechanical Properties
Ductile, Malleable  
Ductile, Sectile  

Magnetic Properties

Magnetic Characteristics
  
  

Specific Gravity
8.65  
36
11.85  
22

Magnetic Ordering
Diamagnetic  
Diamagnetic  

Electrical Properties
  
  

Electrical Property
Semiconductor  
Conductor  

Resistivity
72.70 nΩ·m  
36
0.18 nΩ·m  
99+

Electrical Conductivity
0.14 106/cm Ω  
15
0.06 106/cm Ω  
32

Electron Affinity
0.00 kJ/mol  
40
19.20 kJ/mol  
32

Thermal Properties

Specific Heat
0.23 J/(kg K)  
26
0.13 J/(kg K)  
39

Molar Heat Capacity
26.02 J/mol·K  
32
26.32 J/mol·K  
29

Thermal Conductivity
96.60 W/m·K  
16
46.10 W/m·K  
33

Critical Temperature
Not Available  
Not Available  

Thermal Expansion
30.80 µm/(m·K)  
10
29.90 µm/(m·K)  
12

Enthalpy
  
  

Enthalpy of Vaporization
100.00 kJ/mol  
99+
162.10 kJ/mol  
99+

Enthalpy of Fusion
6.19 kJ/mol  
99+
4.27 kJ/mol  
99+

Enthalpy of Atomization
113.00 kJ/mol  
99+
179.90 kJ/mol  
99+

Standard Molar Entropy
51.80 J/mol.K  
27
64.20 J/mol.K  
19

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