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Hafnium vs Technetium


Technetium vs Hafnium


Periodic Table

Symbol
Hf   
Tc   

Group Number
4   
14
7   
11

Period Number
6   
5   

Block
d block   
d block   

Element Family
Transition Metal   
Transition Metal   

CAS Number
7440586   
30
7440268   
99+

Space Group Name
P63/mmc   
P63/mmc   

Space Group Number
194.00   
5
194.00   
5

Facts

Interesting Facts
  • Hafnium metal is highly reactive, hence not found free in nature.
  • Hafnium metal as predicated after Mendeleev finished his periodic table.
  
  • Original name of Technetium was Masurium.
  • At the time of its discovery it found in sample of Molybdenum.
  

Sources
By-product Zirconium Refining   
Made by Bombarding Molybdenum with Deuterons   

History
  
  

Who Discovered
Dirk Coster and George de Hevesy   
Emilio Segrè and Carlo Perriero   

Discovery
In 1922   
In 1937   

Abundance
  
  

Abundance In Universe
7 * 10-8 %   
25
Not Available   

Abundance In Sun
~0.0000001 %   
26
~-9999 %   

Abundance In Meteorites
0.00 %   
37
Not Available   

Abundance In Earth's Crust
0.00 %   
31
Not Available   

Abundance In Oceans
0.00 %   
27
Not Available   

Uses

Uses & Benefits
  • It has an ability to absorb neutrons and hence it is used to make control rods in nuclear submarines. And this metal is also used in Plasma welding torches.
  • It alloys with iron, titanium and niobium are very useful.
  
  • Technetium is a radioactive metal and hence it is used for medical studies and other research purposes.
  

Industrial Uses
Ammunition Industry   
NA   

Medical Uses
NA   
NA   

Other Uses
Alloys, In Nuclear Reactors, Nuclear Research, Research Purposes   
Alloys, Nuclear Research, Research Purposes   

Biological Properties
  
  

Toxicity
Toxic   
Low Toxic   

Present in Human Body
No   
No   

In Blood
Not Available   
0.00 Blood/mg dm-3   
37

In Bone
Not Available   
0.00 p.p.m.   
36

Physical Properties

Melting Point
2,150.00 °C   
10
2,200.00 °C   
9

Boiling Point
5,400.00 °C   
5
4,877.00 °C   
7

Appearance
  
  

Physical State
Solid   
Solid   

Color
Gray   
Shiny Gray   

Luster
Metallic   
NA   

Hardness
  
  

Mohs Hardness
5.50   
7
Not Available   

Brinell Hardness
1,450.00 MPa   
6
Not Available   

Vickers Hardness
1,520.00 MPa   
5
Not Available   

Speed of Sound
3,010.00 m/s   
27
16,200.00 m/s   
1

Optical Properties
  
  

Allotropes
No   
No   

α Allotropes
Not Available   
Not Available   

β Allotropes
Not Available   
Not Available   

γ Allotropes
Not Available   
Not Available   

Chemical Properties

Chemical Formula
Hf   
Tc   

Isotopes
  
  

Known Isotopes
32   
7
18   
21

Electronegativity
  
  

Pauling Electronegativity
1.30   
32
1.90   
11

Allred Rochow Electronegativity
1.23   
25
1.36   
20

Allen Electronegativity
1.16   
37
1.51   
28

Electropositivity
  
  

Pauling Electropositivity
2.70   
22
2.10   
99+

Ionization Energies
  
  

1st Energy Level
658.50 kJ/mol   
40
702.00 kJ/mol   
36

2nd Energy Level
1,440.00 kJ/mol   
99+
1,470.00 kJ/mol   
99+

3rd Energy Level
2,250.00 kJ/mol   
99+
2,850.00 kJ/mol   
33

4th Energy Level
3,216.00 kJ/mol   
99+
Not Available   

Electrochemical Equivalent
1.66 g/amp-hr   
99+
0.52 g/amp-hr   
99+

Electron Work Function
3.90 eV   
27
Not Available   

Other Chemical Properties
Anti Corrosion, Ionization, Radioactive Isotopes, Solubility   
Anti Corrosion, Ionization, Radioactive Isotopes, Radioactivity, Solubility   

Atomic Properties

Atomic Number
72   
99+
43   
99+

Electron Configuration
[Xe] 4f14 5d2 6s2   
[Kr] 4d5 5s2   

Crystal Structure
Hexagonal Close Packed (HCP)   
Hexagonal Close Packed (HCP)   

Crystal Lattice
BCC-Crystal-Structure-.jpg#100   
HCP-Crystal-Structure-of-Technetium.jpg#100   

Atom
  
  

Number of Protons
72   
99+
43   
99+

Number of Neutrons
106   
29
55   
99+

Number of Electrons
72   
99+
43   
99+

Radius of an Atom
  
  

Atomic Radius
159.00 pm   
28
136.00 pm   
99+

Covalent Radius
175.00 pm   
23
147.00 pm   
37

Van der Waals Radius
200.00 pm   
28
200.00 pm   
28

Atomic Weight
178.49 amu   
39
98.00 amu   
99+

Atomic Volume
13.60 cm3/mol   
38
8.50 cm3/mol   
99+

Adjacent Atomic Numbers
  
  

Previous Element
Lutetium
  
Molybdenum
  

Next Element
Tantalum
  
Ruthenium
  

Valence Electron Potential
81.00 (-eV)   
16
180.00 (-eV)   
3

Lattice Constant
319.64 pm   
99+
273.50 pm   
99+

Lattice Angles
π/2, π/2, 2 π/3   
π/2, π/2, 2 π/3   

Lattice C/A Ratio
1.58   
12
1.60   
5

Mechanical Properties

Density
  
  

Density At Room Temperature
13.31 g/cm3   
26
11.00 g/cm3   
34

Density When Liquid (at m.p.)
12.00 g/cm3   
12
Not Available   

Tensile Strength
445.00 MPa   
8
Not Available   

Viscosity
Not Available   
Not Available   

Vapor Pressure
  
  

Vapor Pressure at 2000 K
0.00 (Pa)   
24
Not Available   

Elasticity properties
  
  

Shear Modulus
30.00 GPa   
23
Not Available   

Bulk Modulus
110.00 GPa   
15
Not Available   

Young's Modulus
78.00 GPa   
25
Not Available   

Poisson Ratio
0.37   
7
Not Available   

Other Mechanical Properties
Ductile, Malleable   
NA   

Magnetic Properties

Magnetic Characteristics
  
  

Specific Gravity
13.31   
18
11.50   
24

Magnetic Ordering
Paramagnetic   
Paramagnetic   

Electrical Properties
  
  

Electrical Property
Conductor   
Conductor   

Resistivity
331.00 nΩ·m   
14
200.00 nΩ·m   
18

Electrical Conductivity
0.03 106/cm Ω   
39
0.07 106/cm Ω   
30

Electron Affinity
0.00 kJ/mol   
40
53.00 kJ/mol   
18

Thermal Properties

Specific Heat
0.14 J/(kg K)   
37
0.21 J/(kg K)   
29

Molar Heat Capacity
25.73 J/mol·K   
36
24.27 J/mol·K   
99+

Thermal Conductivity
23.00 W/m·K   
99+
50.60 W/m·K   
30

Critical Temperature
Not Available   
Not Available   

Thermal Expansion
5.90 µm/(m·K)   
99+
7.10 µm/(m·K)   
99+

Enthalpy
  
  

Enthalpy of Vaporization
661.10 kJ/mol   
5
660.00 kJ/mol   
6

Enthalpy of Fusion
25.10 kJ/mol   
8
23.01 kJ/mol   
9

Enthalpy of Atomization
703.00 kJ/mol   
5
649.00 kJ/mol   
8

Standard Molar Entropy
43.60 J/mol.K   
34
181.10 J/mol.K   
2

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