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Bismuth vs Cadmium


Cadmium vs Bismuth


Periodic Table

Symbol
Bi   
Cd   

Group Number
15   
3
12   
6

Period Number
6   
5   

Block
p block   
d block   

Element Family
Post-​Transition   
Transition Metal   

CAS Number
7440699   
22
7440439   
99+

Space Group Name
C12/m1   
P63/mmc   

Space Group Number
12.00   
12
194.00   
5

Facts

Interesting Facts
  • Bismuth metal is soluble and reacts with concentrated nitric acid.
  • It oxides are used as a yellow pigment in paint. Bismuth chloride oxide BiClO gives a pearly texture to cosmetics.
  
  • Naturally occurring minor elements include Cadmium.
  • Cadmium is released into atmosphere to control volcanic eruption and forest fires.
  • It is used for electroplating of Steel for corrosion resistance.
  • It can absorb neutrons and used in nuclear reactor to control atomic fission.
  

Sources
Found in Minerals, Mining, Ores of Minerals   
Found As a By-product, Found in Minerals, Mining   

History
  
  

Who Discovered
Claude François Geoffroy   
Karl Samuel Leberecht Hermann and Friedrich Stromeyer   

Discovery
In 1753   
In 1817   

Abundance
  
  

Abundance In Universe
7 * 10-8 %   
25
2 * 10-7 %   
22

Abundance In Sun
~0.000006 %   
14
~0.0000006 %   
21

Abundance In Meteorites
0.00 %   
99+
0.00 %   
31

Abundance In Earth's Crust
0.00 %   
99+
0.00 %   
99+

Abundance In Oceans
0.00 %   
24
0.00 %   
28

Abundance In Humans
Not Available   
0.00 %   
11

Uses

Uses & Benefits
  • Tin and bismuth alloys have a very low melting point and hence it is used in fire detector and the fire extinguishers. It also used in electric solders and fuses.
  
  • It has very limited uses as it is a toxic metal and it can cause birth defects, cancer, etc.
  • Almost 80% of Cadmium metal is used in Nickel cadmium Batteries and now it is getting replaced with nickel hydride.
  

Industrial Uses
Automobile Industry, Chemical Industry, Electrical Industry, Electronic Industry   
Aerospace Industry, Ammunition Industry, Chemical Industry, Electrical Industry, Electronic Industry   

Medical Uses
Pharmaceutical Industry   
NA   

Other Uses
Alloys   
Alloys   

Biological Properties
  
  

Toxicity
Low Toxic   
Toxic   

Present in Human Body
Yes   
Yes   

In Blood
0.02 Blood/mg dm-3   
20
0.01 Blood/mg dm-3   
24

In Bone
0.20 p.p.m.   
22
1.80 p.p.m.   
15

Physical Properties

Melting Point
271.30 °C   
99+
320.90 °C   
99+

Boiling Point
1,560.00 °C   
99+
765.00 °C   
99+

Appearance
  
  

Physical State
Solid   
Solid   

Color
Silver   
Silvery Bluish-Gray   

Luster
Metallic   
Metallic   

Hardness
  
  

Mohs Hardness
2.25   
15
2.00   
16

Brinell Hardness
70.00 MPa   
99+
203.00 MPa   
39

Speed of Sound
1,790.00 m/s   
99+
2,310.00 m/s   
39

Optical Properties
  
  

Reflectivity
Not Available   
67.00 %   
11

Allotropes
No   
No   

α Allotropes
Not Available   
Not Available   

β Allotropes
Not Available   
Not Available   

γ Allotropes
Not Available   
Not Available   

Chemical Properties

Chemical Formula
Bi   
Cd   

Isotopes
  
  

Known Isotopes
33   
6
34   
5

Electronegativity
  
  

Pauling Electronegativity
2.02   
6
1.69   
17

Sanderson Electronegativity
2.34   
3
1.98   
9

Allred Rochow Electronegativity
1.67   
6
1.46   
15

Mulliken-Jaffe Electronegativity
2.15   
4
1.53   
13

Allen Electronegativity
2.01   
4
1.52   
27

Electropositivity
  
  

Pauling Electropositivity
1.98   
99+
2.31   
37

Ionization Energies
  
  

1st Energy Level
703.00 kJ/mol   
35
867.80 kJ/mol   
11

2nd Energy Level
1,610.00 kJ/mol   
33
1,631.40 kJ/mol   
32

3rd Energy Level
2,466.00 kJ/mol   
99+
3,616.00 kJ/mol   
13

4th Energy Level
4,370.00 kJ/mol   
28
Not Available   

5th Energy Level
5,400.00 kJ/mol   
30
Not Available   

6th Energy Level
8,520.00 kJ/mol   
19
Not Available   

Electrochemical Equivalent
2.60 g/amp-hr   
19
2.10 g/amp-hr   
27

Electron Work Function
4.22 eV   
22
4.22 eV   
22

Other Chemical Properties
Ionization, Radioactive Isotopes, Solubility   
Chemical Stability, Anti Corrosion, Ionization, Radioactive Isotopes, Solubility   

Atomic Properties

Atomic Number
83   
33
48   
99+

Electron Configuration
[Xe] 4f14 5d10 6s2 6p3   
[Kr] 4d10 5s2   

Crystal Structure
Rhombohedral (RHO)   
Hexagonal Close Packed (HCP)   

Crystal Lattice
RHO-Crystal-Structure-of-Bismuth.jpg#100   
HCP-Crystal-Structure-of-Cadmium.jpg#100   

Atom
  
  

Number of Protons
83   
33
48   
99+

Number of Neutrons
126   
18
64   
99+

Number of Electrons
83   
33
48   
99+

Radius of an Atom
  
  

Atomic Radius
156.00 pm   
29
151.00 pm   
32

Covalent Radius
148.00 pm   
36
144.00 pm   
40

Van der Waals Radius
207.00 pm   
26
158.00 pm   
99+

Atomic Weight
208.98 amu   
29
112.41 amu   
99+

Atomic Volume
21.30 cm3/mol   
14
13.10 cm3/mol   
39

Adjacent Atomic Numbers
  
  

Previous Element
Lead
  
Silver
  

Next Element
Polonium
  
Indium
  

Valence Electron Potential
41.90 (-eV)   
99+
30.00 (-eV)   
99+

Lattice Constant
667.40 pm   
2
297.94 pm   
99+

Lattice Angles
NA   
π/2, π/2, 2 π/3   

Lattice C/A Ratio
Not Available   
1.89   
1

Mechanical Properties

Density
  
  

Density At Room Temperature
9.78 g/cm3   
39
8.65 g/cm3   
99+

Density When Liquid (at m.p.)
10.05 g/cm3   
18
8.00 g/cm3   
28

Tensile Strength
Not Available   
62.00 MPa   
16

Viscosity
Not Available   
Not Available   

Vapor Pressure
  
  

Elasticity properties
  
  

Shear Modulus
12.00 GPa   
99+
19.00 GPa   
35

Bulk Modulus
31.00 GPa   
38
42.00 GPa   
29

Young's Modulus
32.00 GPa   
99+
50.00 GPa   
36

Poisson Ratio
0.33   
11
0.30   
14

Other Mechanical Properties
NA   
Ductile, Malleable   

Magnetic Properties

Magnetic Characteristics
  
  

Specific Gravity
9.79   
30
8.65   
36

Magnetic Ordering
Diamagnetic   
Diamagnetic   

Permeability
0.00 H/m   
6
Not Available   

Susceptibility
0.00   
6
Not Available   

Electrical Properties
  
  

Electrical Property
Semiconductor   
Semiconductor   

Resistivity
1.29 nΩ·m   
99+
72.70 nΩ·m   
36

Electrical Conductivity
0.01 106/cm Ω   
99+
0.14 106/cm Ω   
15

Electron Affinity
91.20 kJ/mol   
11
0.00 kJ/mol   
40

Thermal Properties

Specific Heat
0.12 J/(kg K)   
40
0.23 J/(kg K)   
26

Molar Heat Capacity
25.52 J/mol·K   
37
26.02 J/mol·K   
32

Thermal Conductivity
7.97 W/m·K   
99+
96.60 W/m·K   
16

Critical Temperature
Not Available   
Not Available   

Thermal Expansion
13.40 µm/(m·K)   
28
30.80 µm/(m·K)   
10

Enthalpy
  
  

Enthalpy of Vaporization
151.00 kJ/mol   
99+
100.00 kJ/mol   
99+

Enthalpy of Fusion
10.90 kJ/mol   
33
6.19 kJ/mol   
99+

Enthalpy of Atomization
207.10 kJ/mol   
99+
113.00 kJ/mol   
99+

Standard Molar Entropy
56.70 J/mol.K   
24
51.80 J/mol.K   
27

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