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Cerium vs Hafnium


Hafnium vs Cerium


Periodic Table

Symbol
Ce  
Hf  

Group Number
3  
15
4  
14

Period Number
6  
6  

Block
f block  
d block  

Element Family
Lanthanide  
Transition Metal  

CAS Number
7440451  
99+
7440586  
30

Space Group Name
P63/mmc  
P63/mmc  

Space Group Number
194.00  
7
194.00  
7

Facts

Interesting Facts
  • Cerium is a rare earth metal but still it is not rare at all.
  • It’s non-toxic compound Cerium sulfide has a rich red color and it is used as a pigment.
  • Cerium metal is also used in Flat screen TVs, light bulb, floodlights, etc.
  
  • Hafnium metal is highly reactive, hence not found free in nature.
  • Hafnium metal as predicated after Mendeleev finished his periodic table.
  

Sources
Found in Minerals, Mining, Ores of Minerals  
By-product Zirconium Refining  

History
  
  

Who Discovered
Martin Heinrich Klaproth, Jöns Jakob Berzelius, Wilhelm Hisinger  
Dirk Coster and George de Hevesy  

Discovery
In 1803  
In 1922  

Abundance
  
  

Abundance In Universe
0.00 %  
17
0.00 %  
26

Abundance In Sun
0.00 %  
23
0.00 %  
26

Abundance In Meteorites
0.00 %  
27
0.00 %  
37

Abundance In Earth's Crust
0.01 %  
18
0.00 %  
31

Abundance In Oceans
0.00 %  
33
0.00 %  
27

Abundance In Humans
0.00 %  
24
0.00 %  
14

Uses

Uses & Benefits
  • It is used to include flints for cigarette lighters.
  • Its compound Cerium (Ill) Oxide is used as a catalyst; it is put inside the walls of the oven as it prevents from the buildup of cooking residues.
  
  • It has an ability to absorb neutrons and hence it is used to make control rods in nuclear submarines. And this metal is also used in Plasma welding torches.
  • It alloys with iron, titanium and niobium are very useful.
  

Industrial Uses
Chemical Industry  
Ammunition Industry  

Medical Uses
Medical Research  
-  

Other Uses
Alloys  
Alloys, In Nuclear Reactors, Nuclear Research, Research Purposes  

Biological Properties
  
  

Toxicity
Moderately Toxic  
Toxic  

Present in Human Body
Yes  
No  

In Blood
0.00 Blood/mg dm-3  
30
0.00 Blood/mg dm-3  
40

In Bone
2.70 p.p.m.  
14
0.00 p.p.m.  
99+

Physical

Melting Point
795.00 °C  
99+
2,150.00 °C  
10

Boiling Point
3,257.00 °C  
24
5,400.00 °C  
5

Appearance
  
  

Physical State
Solid  
Solid  

Color
Silvery White  
Gray  

Luster
Lustrous  
Metallic  

Hardness
  
  

Mohs Hardness
2.50  
15
5.50  
7

Brinell Hardness
186.00 MPa  
99+
1,450.00 MPa  
6

Vickers Hardness
210.00 MPa  
99+
1,520.00 MPa  
10

Speed of Sound
2,100.00 m/s  
99+
3,010.00 m/s  
39

Optical Properties
  
  

Refractive Index
2.20  
9
2.00  
15

Reflectivity
68.00 %  
15
71.00 %  
12

Allotropes
No  
No  

α Allotropes
-  
-  

β Allotropes
-  
-  

γ Allotropes
-  
-  

Chemical

Chemical Formula
Ce  
Hf  

Isotopes
  
  

Known Isotopes
30  
9
32  
7

Electronegativity
  
  

Pauling Electronegativity
1.12  
99+
1.30  
33

Sanderson Electronegativity
1.12  
37
1.30  
25

Allred Rochow Electronegativity
1.08  
32
1.23  
26

Mulliken-Jaffe Electronegativity
1.12  
99+
1.30  
33

Allen Electronegativity
1.12  
99+
1.16  
99+

Electropositivity
  
  

Pauling Electropositivity
2.88  
11
2.70  
22

Ionization Energies
  
  

1st Energy Level
534.40 kJ/mol  
99+
658.50 kJ/mol  
40

2nd Energy Level
1,050.00 kJ/mol  
99+
1,440.00 kJ/mol  
99+

3rd Energy Level
1,949.00 kJ/mol  
99+
2,250.00 kJ/mol  
99+

4th Energy Level
3,547.00 kJ/mol  
99+
3,216.00 kJ/mol  
99+

5th Energy Level
6,325.00 kJ/mol  
37
6,585.00 kJ/mol  
33

6th Energy Level
7,490.00 kJ/mol  
38
6,585.00 kJ/mol  
99+

7th Energy level
5,340.00 kJ/mol  
99+
6,580.00 kJ/mol  
99+

8th Energy Level
5,340.00 kJ/mol  
99+
6,580.00 kJ/mol  
99+

9th Energy Level
5,340.00 kJ/mol  
99+
6,585.00 kJ/mol  
38

10th Energy Level
5,340.00 kJ/mol  
99+
6,590.00 kJ/mol  
40

11th Energy Level
5,340.00 kJ/mol  
99+
6,585.00 kJ/mol  
40

12th Energy Level
5,340.00 kJ/mol  
99+
6,580.00 kJ/mol  
99+

13th Energy Level
5,650.00 kJ/mol  
99+
6,580.00 kJ/mol  
35

14th Energy Level
5,340.00 kJ/mol  
99+
658.50 kJ/mol  
99+

15th Energy Level
53,400.00 kJ/mol  
99+
65,800.00 kJ/mol  
34

16th Energy Level
53,400.00 kJ/mol  
99+
658.50 kJ/mol  
99+

17th Energy Level
534.40 kJ/mol  
99+
658.50 kJ/mol  
99+

18th Energy Level
5,340.00 kJ/mol  
99+
6,585.00 kJ/mol  
36

19th Energy Level
534.40 kJ/mol  
99+
658.50 kJ/mol  
99+

20th Energy Level
534.00 kJ/mol  
99+
658.00 kJ/mol  
37

21st Energy Level
5,346.00 kJ/mol  
24
658.50 kJ/mol  
99+

22nd Energy Level
594.00 kJ/mol  
99+
658.00 kJ/mol  
31

23rd Energy Level
5,346.00 kJ/mol  
26
658.50 kJ/mol  
99+

24th Energy Level
565.50 kJ/mol  
99+
658.50 kJ/mol  
31

25th Energy Level
534.40 kJ/mol  
99+
658.00 kJ/mol  
33

26th Energy Level
565.50 kJ/mol  
99+
658.50 kJ/mol  
32

27th Energy Level
565.50 kJ/mol  
99+
658.50 kJ/mol  
33

28th Energy Level
565.50 kJ/mol  
99+
658.50 kJ/mol  
38

29th Energy Level
565.50 kJ/mol  
99+
658.50 kJ/mol  
39

30th Energy Level
594.00 kJ/mol  
99+
658.00 kJ/mol  
35

Electrochemical Equivalent
1.74 g/amp-hr  
99+
1.66 g/amp-hr  
99+

Electron Work Function
2.84 eV  
99+
3.90 eV  
36

Other Chemical Properties
Chemical Stability, Anti Corrosion, Ionization, Radioactive Isotopes, Solubility  
Anti Corrosion, Ionization, Radioactive Isotopes, Solubility  

Atomic

Atomic Number
58  
99+
72  
99+

Electron Configuration
[Xe] 4f1 5d1 6s2  
[Xe] 4f14 5d2 6s2  

Crystal Structure
Double Hexagonal Close Packed (DHCP)  
Hexagonal Close Packed (HCP)  

Crystal Lattice
DHCP-Crystal-Structure-of-Cerium.jpg#100  
BCC-Crystal-Structure-.jpg#100  

Atom
  
  

Number of Protons
58  
99+
72  
99+

Number of Neutrons
82  
99+
106  
30

Number of Electrons
58  
99+
72  
99+

Radius of an Atom
  
  

Atomic Radius
181.80 pm  
14
159.00 pm  
30

Covalent Radius
204.00 pm  
8
175.00 pm  
25

Van der Waals Radius
235.00 pm  
21
200.00 pm  
35

Atomic Weight
140.12 amu  
99+
178.49 amu  
39

Atomic Volume
20.67 cm3/mol  
27
13.60 cm3/mol  
99+

Adjacent Atomic Numbers
  
  

Previous Element
Lanthanum
  
Lutetium
  

Next Element
Tantalum
  

Valence Electron Potential
41.78 (-eV)  
99+
81.00 (-eV)  
16

Lattice Constant
362.00 pm  
38
319.64 pm  
99+

Lattice Angles
π/2, π/2, 2 π/3  
π/2, π/2, 2 π/3  

Lattice C/A Ratio
1.59  
31
1.58  
34

Mechanical

Density
  
  

Density At Room Temperature
6.77 g/cm3  
99+
13.31 g/cm3  
27

Density When Liquid (at m.p.)
6.55 g/cm3  
99+
12.00 g/cm3  
31

Tensile Strength
270.00 MPa  
17
445.00 MPa  
9

Viscosity
0.00  
23
0.00  
28

Vapor Pressure
  
  

Vapor Pressure at 1000 K
0.00 (Pa)  
36
0.00 (Pa)  
37

Vapor Pressure at 2000 K
1.04 (Pa)  
13
0.00 (Pa)  
25

Elasticity properties
  
  

Shear Modulus
13.50 GPa  
99+
30.00 GPa  
27

Bulk Modulus
21.50 GPa  
99+
110.00 GPa  
15

Young's Modulus
33.60 GPa  
99+
78.00 GPa  
27

Poisson Ratio
0.24  
27
0.37  
7

Other Mechanical Properties
Ductile, Malleable  
Ductile, Malleable  

Magnetic

Magnetic Characteristics
  
  

Specific Gravity
6.77  
99+
13.31  
30

Magnetic Ordering
Paramagnetic  
Paramagnetic  

Permeability
0.00 H/m  
7
0.00 H/m  
9

Susceptibility
0.00  
24
0.00  
13

Electrical Properties
  
  

Electrical Property
Conductor  
Conductor  

Resistivity
828.00 nΩ·m  
3
331.00 nΩ·m  
14

Electrical Conductivity
0.01 106/cm Ω  
99+
0.03 106/cm Ω  
99+

Electron Affinity
50.00 kJ/mol  
26
0.00 kJ/mol  
99+

Thermal

Specific Heat
0.19 J/(kg K)  
33
0.14 J/(kg K)  
38

Molar Heat Capacity
26.94 J/mol·K  
30
25.73 J/mol·K  
99+

Thermal Conductivity
11.30 W/m·K  
99+
23.00 W/m·K  
99+

Critical Temperature
1,071.00 K  
99+
2,500.00 K  
11

Thermal Expansion
6.30 µm/(m·K)  
99+
5.90 µm/(m·K)  
99+

Enthalpy
  
  

Enthalpy of Vaporization
414.00 kJ/mol  
22
661.10 kJ/mol  
6

Enthalpy of Fusion
5.46 kJ/mol  
99+
25.10 kJ/mol  
8

Enthalpy of Atomization
381.00 kJ/mol  
31
703.00 kJ/mol  
5

Standard Molar Entropy
72.00 J/mol.K  
12
43.60 J/mol.K  
99+

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